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Proefschrift

Deciphering the atomic structure of the electrified metal oxide-electrolyte interface

Humanity stands at a pivotal juncture, facing the dual challenge of environmental sustainability and rapid population growth, projected to exceed 11 billion by century’s end.

Auteur
N. Deka
Datum
03 april 2025
Links
Thesis in Leiden Repository

Addressing this crisis necessitates transformative advancements in energy and chemical production, aligning global industry with ecological constraints. Central to this transition is electrocatalysis, a process that enables the conversion of renewable electricity into chemical energy, facilitating sustainable fuel and chemical synthesis. Key applications include the electrochemical reduction of CO₂ into valuable hydrocarbons and the production of green hydrogen, critical for decarbonizing industrial processes. Metal oxides, widely employed in electrocatalysis, play a fundamental role in energy conversion, yet their interfacial mechanisms remain poorly understood. Advanced characterization techniques, particularly X-ray absorption spectroscopy (XAS), provide unprecedented insights into the electrode-electrolyte interface, guiding the rational design of high-performance catalysts. This research leverages XAS to elucidate the electronic and structural dynamics of metal oxides, paving the way for optimized electrocatalytic systems and a more sustainable chemical industry.

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