Lies Bouwman
Director of education / professor of Inorganic chemistry
- Name
- Prof.dr. E. Bouwman
- Telephone
- +31 71 527 4550
- bouwman@chem.leidenuniv.nl
- ORCID iD
- 0000-0001-7762-3968
Central to the research of Lies Bouwman is the aim to gain understanding of transition metal complexes and their properties and reactivity at the molecular level. She then uses this understanding to ‘teach’ metal complexes to perform new catalytic reactions.
More information about Lies Bouwman
PhD Candidates
News
Teaching
Former PhD candidates
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Michael Meijer -
Konstantin Kottrup
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Feng Jiang
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Vincent H. S. van Rixel
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Siyuan Luo
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Lucien Nathanaël Lameijer
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Jordi-Amat Cuello Garibo
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Gamze Gezer
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Xue Liu
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Tom van Dijkman
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Erica Cecilia Maria Ording-Wenker
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Bart Limburg
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Sipeng Zheng
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Saeed Raoufmoghaddam
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Sebastiaan Akerboom
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Azadeh Bahreman
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Sven Haskes
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Tiddo Mooibroek
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Jimmy van Rijn
Curriculum Vitae
Personal information
Nationality: Dutch
Date of birth: 17 March 1962
Education
1990 PhD, Faculty of Mathematics & Natural Sciences, Leiden University, The Netherlands, 28 February
Thesis title: “Modelling the blue copper site with imidazole-thioether ligands”
Advisor: Prof. Dr. J. Reedijk.
1986 MSc in Chemistry, Faculty of Mathematics & Natural Sciences, Leiden University, The Netherlands
Current and previous research positions
2010 - now Full Professor in Inorganic Chemistry, Leiden Institute of Chemistry, Leiden University, the Netherlands
2000 – 2010 Associate Professor, Leiden Institute of Chemistry, Leiden University (NL)
1996 – 2000 Assistant Professor, Leiden Institute of Chemistry, Leiden University (NL)
1991 – 1996 Fellow of the Royal Netherlands Academy of Arts and Sciences, Leiden Institute of Chemistry, Leiden University, the Netherlands (Prof. J. Reedijk)
1990 – 1991 Postdoctoral Researcher, Indiana University, Bloomington, Indiana, USA, supported by a NATO fellowship (Prof. G. Christou)
1990 - 1990 Postdoctoral Researcher, Delft University of Technology, the Netherlands (Prof. H. van Bekkum)
Grants, awards, recognitions since 2010
2014 Contract research for Corbion (k€ 120)
2014 FOM ‘CO2 neutral fuels’ programme grant with M.T.M. Koper and D.G.H. Hetterscheid (k€ 464)
2013 FES SmartMix CatchBio grant (k€ 188)
2012 NWO HRSMC Graduate School programme (k€ 200)
2011 FOM TBSC grant with S.A. Bonnet and G. Mul (Twente) (k€ 250)
2010 NRSC-C Top research school (k€ 400)
2010 FES-HTSM NanoNextNL (k€ 232.5)
2010 STW project grant generated from patent revenues (k€ 273.5)
Contribution to teaching and supervision
Teaching: course for BSc Molecular Science and Technology (Leiden/Delft): Chemistry and Applications of Transition Metals.
Teaching: course for BSc Life Science and Technology (Leiden/Delft): Inorganic Chemistry of Life.
Teaching: Course for MSc Chemistry Leiden University: Organometallic Chemistry and Homogeneous Catalysis.
Teaching: Contributions to courses for the national graduate school Holland Research School for Molecular Chemistry (HRSMC; Electrochemistry in “Physical Methods in Inorganic Chemisty”) and Netherlands Institute for Research in Catalysis (NIOK; Homogeneous Catalysis in “Catalysis, an integrated approach”).
Outreach: guest lectures for high school (Chemistry of transition metals; Chemistry of paint); lectures for children of elementary schools and refugee children in the ‘Junior Science Lab’ (What is Chemistry?).
Supervision of ~25 PhD students and >10 postdoctoral fellows since 1996. Current employment of recent PhD students and postdocs: E.C.M. Ording-Wenker, Avantium Chemicals; X. Liu, PD Leiden University; B. Limburg, PD Oxford University; S. Raoufmoghaddam, PD Oxford University; S. Akerboom, Nalco; T.J. Mooibroek, University of Amsterdam (Vidi grant); R. Angamuthu, assistant professor, Indian Institute of Technology Kanpur, India; F. Terrade, Akzo Nobel; Y. Gloaguen, PD University of Amsterdam; J.A. van Rijn; Hexion Specialty Chemicals.
Other responsibilities since 2010
- Editorial board member for the European Journal of Inorganic Chemistry (2006-2016), Applied Organometallic Chemistry (since 2009).
- Board member General board of Leiden University Fund (LUF; since 2011)
- Board member of the Division of Inorganic Chemistry of EuCheMS (since 2012)
- Advisor for the 3rd EuCheMS Inorganic Chemistry Conference (Wroclaw, Poland, 2015).
- Board member of the study group Coordination Chemistry and Homogeneous Catalysis of the Dutch Chemical Sciences (CW; since 2014)
- Chairman/coordinator of the session “Coordination Chemistry” of the Dutch Conference on Catalysis (2013, 2015).
- Member of the Education committee of the graduate school NIOK (2005-2014).
- Member of the Exam Committee of the MSc programme Chemistry (2009-2013)
- Director of Education of the MSc programme Chemistry (since 2013)
- Member of the ‘Permanent Committee for Academic Practice’ (WECO; since 2014)
- Member of review panel for the Netherlands Organisation for Scientific Research (NWO), Academy of Finland.
- External member to PhD committees in Utrecht, Amsterdam, Nijmegen.
- Reviewer for Nature Communications, Angewandte Chemie, Journal of the American Chemical Society, Inorganic Chemistry, Organometallics, Dalton Transactions, Applied Catalysis A, ACS Catalysis and various inorganic chemistry journals.
Publication record including five recent representative publications
Over 180 papers with >3400 citations, H-index 29 (Web of Science); 3 book chapters, 11 patents
Full publication record: ResearcherID
- Liu X., Fu W.T., Bouwman E., One-step growth of lanthanoid metal-organic framework (MOF) films under solvothermal conditions for temperature sensing. Chem. Commun. 2016, 52(42) 6926-6929.
- Ording-Wenker E.C.M., Plas M. van der, Siegler M.A., Fonseca Guerra C., Bouwman E., Protonation of the biologically relevant CuII µ-thiolate complex: ligand dissociation or formation of a protonated CuI disulfide species? Chem. – Eur. J. 2014, 20, 16913-16921.
- Ording-Wenker E.C.M., Plas M. van der, Siegler M.A., Bonnet S.A., Bickelhaupt F.M., Fonseca Guerra C., Bouwman E., Thermodynamics of the CuII µ-thiolate and CuI disulfide equilibrium: a combined experimental and theoretical study. Inorg. Chem. 2014, 53, 8494-8504.
- Raoufmoghaddam S., Rood M.T.M., Buijze F.K.W., Drent E., Bouwman E., Catalytic Conversion of γ‑Valerolactone to ε-Caprolactam: towards Nylon from Renewable Feedstock. ChemSusChem. 2014, 7, 1984-1990.
- Raoufmoghaddam S., Drent E., Bouwman E., Chemo- and regioselective homogeneous rhodium-catalyzed hydroamidomethylation of terminal alkenes to N-alkylamides. ChemSusChem. 2013, 6, 1759-1773.
Outreach: Based on our publication in ChemSusChem (2014): news item at the website of Leiden University, in Mare (Leiden University paper; 4dec14; local newspaper Leidsch Dagblad (3dec14), chemical magazine C2W (19dec14), and an article in the popular science magazine Quest (issue March 2015).
Presentations including five presentations at international conferences since 2010
~20 invited presentations at universities, institutes and international conferences since 2010.
- Biomimetic Redox Reactions of the CuII Thiolate Complex; 3rd EuCheMS Inorganic Chemistry Conference, June 28-July 1, 2015, Wroclaw (Poland).
- Development of homogeneous catalysts for novel reactions involving CO and H2. Small Molecule Activation Conference, July 15-18, 2014, Chicago (USA).
- From Renewable Feedstock to “Green” Nylon: Catalytic Conversion of γ-Valerolactone to ε-Caprolactam; CatchBio International Open Symposium “New concepts in selective biomass conversions”, January 20-21, 2015, Aachen (Germany).
- Development of Homogeneous Catalysts for Novel Reactions; Reductive Amidation: a Reaction with Great Potential. 2nd EuCheMS Inorganic Chemistry Conference, July 7-11, 2013, Jerusalem (Israel).
- Copper compounds catching carbon dioxide. Gordon Research Conference Metals in Biology, January 30-February 4, 2011, Ventura (USA).
Director of education / professor of Inorganic chemistry
- Wiskunde en Natuurwetenschappen
- Leiden Institute of Chemistry
- LIC/Energy & Sustainability
- Shirvan A., Golchoubian H. & Bouwman E. (2019), Syntheses and chromotropic behavior of two halo bridged dinuclear copper(II) complexes containing pyridine-based bidentate ligand, Journal of Molecular Structure 1195: 769-777.
- Luo S., Siegler M.A. & Bouwman E. (2019), Transition Metal Compounds of Pyridine-Amide-Functionalized Carbene Ligands: Synthesis, Structure, and Electrocatalytic Properties in Proton Reduction, European Journal of Inorganic Chemistry 2019(5): 617-627.
- Jiang F., Siegler M.A. & Bouwman E. (2018), The Reactivity of Fe-II and Co-II Disulfide Compounds with Dihydrogen Peroxide, European Journal of Inorganic Chemistry 2018(43): 4696-4701.
- Jiang F., Siegler M.A. & Bouwman E. (2019), Synthesis and characterization of a series of transition metal compounds of thioether and disulfide ligands, Inorganica Chimica Acta 486: 135-140.
- Jiang F., Siegler M.A., Sun X., Jiang L., Fonseca Guerra C. & Bouwman E. (2018), Redox Interconversion between Cobalt(III) Thiolate and Cobalt(II) Disulfide Compounds, Inorganic Chemistry 57(15): 8796-8805.
- Jiang F., Siegler M.A. & Bouwman E. (2018), A tetranuclear fluorido-bridged iron compound: Fluoride abstraction from the tetrafluoridoborate anion, Inorganic Chemistry Communications 94: 53-56.
- Luo S., Bruggeman D.F., Siegler M.A. & Bouwman E. (2018), Can pendant pyridyl arm assist the proton delivery in electrocatalysis?, Inorganica Chimica Acta 477: 24-30.
- Luo S., Siegler M.A. & Bouwman E. (2018), Dinuclear Nickel Complexes of Thiolate-Functionalized Carbene Ligands and Their Electrochemical Properties, Organometallics 37(5): 740-747.
- Fu W., Dijkman T.F. van, Macedo Coelho Lima L., Jiang F., Schneider G.F. & Bouwman E. (2017), Ultrasensitive Ethene Detector Based on a Graphene-Copper(I) Hybrid Material, Nano Letters 17(12): 7980-7988.
- Gezer G., Durán Jiménez D., Siegler M.A. & Bouwman E. (2017), Synthesis and Characterization of Trinuclear [Ni2Ru] Complexes with Bridging Thiolate or Selenolate Donors for Electrocatalytic Proton Reduction, European Journal of Inorganic Chemistry 2017(43): 5027-5032.
- Gezer G., Verbeek S., Siegler M.A. & Bouwman E. (2017), Nickel-ruthenium-based complexes as biomimetic models of [NiFe] and [NiFeSe] hydrogenases for dihydrogen evolution, Dalton Transactions 46(39): 13590-13596.
- Gezer G., Jiménez Durán D., Siegler M.A. & Bouwman E. (2017), Electrocatalytic proton reduction by a model for [NiFeSe] hydrogenases, Dalton Transactions 46(23): 7506-7514.
- Dijkman T.F. van, Bruijn H.M. de, Brevé T.G., Meijeren B. van, Siegler M.A. & Bouwman E. (2017), Extremely bulky copper(I) complexes of [HB(3,5-{1-naphthyl}(2)pz)(3)](-) and [HB(3,5-{2-naphthyl}(2)pz)(3)](-) and their self-assembly on graphene, Dalton Transactions 46(19): 6433-6446.
- Terrade F.G., Krieken J. van, Verkuijl B.J.V. & Bouwman E. (2017), Catalytic cracking of Lactide and Poly(Lactid Acid) to Acrylic Acid at Low Temperatures, ChemSusChem 10(9): 1904-1908.
- Limburg B., Gloaguen Y., Bruijn H.M. de, Drent E. & Bouwman E. (2017), Palladium‐Catalyzed Isomerization/(Cyclo)carbonylation of Pentenamides: a Mechanistic Study of the Chemo‐ and Regioselectivity, CHEMCATCHEM 9(15): 2961-2971.
- Liu X., Siegler M.A., Hilbers M. & Bouwman E. (2017), Synthesis, structure and photoluminescence properties of lanthanoid coordination polymers based on tetra(3,5-dicarboxyphenoxymethyl) methane, Polyhedron 123: 1-8.
- Liu X., Fu W.T. & Bouwman E. (2016), One-step growth of lanthanoid metal-organic framework (MOF) films under solvothermal conditions for temperature sensing, CHEMICAL COMMUNICATIONS 52(42): 6926-6929.
- Limburg B., Wermink J., Nielen S.S. van, Kortlever R., Koper M.T.M., Bouwman E. & Bonnet S. (2016), Kinetics of Photocatalytic Water Oxidation at Liposomes: Membrane Anchoring Stabilizes the Photosensitizer, ACS CATALYSIS 6(9): 5968-5977.
- Limburg B., Bouwman E. & Bonnet S.A. (2016), Rate and Stability of Photocatalytic Water Oxidation using [Ru(bpy)(3)](2+) as Photosensitizer, ACS CATALYSIS 6(8): 5273-5284.
- Liu X. & Bouwman E. (2016), Synthesis and photophysical properties of a highly luminescent Eu-III-containing hybrid thin film, POLYHEDRON 118: 25-29.
- Limburg B., Bouwman E. & Bonnet S.A. (2016), Effect of Liposomes on the Kinetics and Mechanism of the Photocatalytic Reduction of Methyl Viologen, JOURNAL OF PHYSICAL CHEMISTRY B 120(28): 6969-6975.
- Dijkman T.F. van, Siegler M.A. & Bouwman E. (2016), Copper(I) Complexes of Naphthyl-Substituted Fluorinated Trispyrazolylborate Ligands with Ethene and Carbon Monoxide, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2016(15-16): 2586-2594.
- Liu X., Siegler M.A. & Bouwman E. (2016), Ratiometric Thermometer Based on a Lanthanoid Coordination Polymer, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2016(18): 2984-2988.
- Liu X., González-Castro A., Mutikainen I., Pevec A., Teat S.J., Gamez P., Sanchez Costa J., Bouwman E. & Reedijk J. (2016), Zinc and cadmium halide compounds with the tridentate ligand 2-(methylsulfanyl)-N-(pyridin-2-ylmethylidene)aniline showing yellow luminescence, POLYHEDRON 110: 100-105.
- Zheng S., Reintjens N.R.M., Siegler M.A., Roubeau O., Bouwman E., Rudavskyi A., Havenith R.W.A. & Bonnet S. (2016), Stabilization of the Low-Spin State in a Mononuclear Iron(II) Complex and High-Temperature Cooperative Spin Crossover Mediated by Hydrogen Bonding, CHEMISTRY-A EUROPEAN JOURNAL 22(1): 331-339.
- Luo S., Siegler M.A. & Bouwman E. (2016), Nickel complexes of pyridine-functionalized N-heterocyclic carbenes: syntheses, structures, and activity in electrocatalytic hydrogen production, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2016(28): 4693-4700.
- Dijkman T.F. van, Bouwman E., Fu W. & Schneider G.F. (2016), A device for the highly sensitive detection of a gaseous analyte ( octrooi nr. PCT/EP2016/052941), (Leiden University). [patent]
- Ording-Wenker E.C.M., Siegler M.A., Lutz M. & Bouwman E. (2015), Catalytic catechol oxidation by copper complexes: development of a structure-activity relationship, Dalton Transactions 44(27): 12196-12209.
- Dijkman T.F. van, Siegler M.A. & Bouwman E. (2015), Highly tunable fluorinated trispyrazolylborates [HB(3-CF3-5-{4-RPh}pz)(3)](-) (R = NO2, CF3, Cl, F, H, OMe and NMe2) and their copper(I) complexes, Dalton Transactions 44(48): 21109-21123.
- Limburg B., Bouwman E. & Bonnet S.A. (2015), Catalytic photoinduced electron transport across a lipid bilayer mediated by a membrane-soluble electron relay, Chemical Communications 51(96): 17128-17131.
- Liu X., Akerboom S., Jong M. de, Mutikainen I., Tanase S., Meijerink A. & Bouwman E. (2015), Mixed-Lanthanoid Metal-Organic Framework for Ratiometric Cryogenic Temperature Sensing, Inorganic Chemistry 54(23): 11323-11329.
- Dijkman T.F. van, Bruijn H.M. de, Siegler M.A. & Bouwman E. (2015), Bright Cyan Phosphorescence of a (Phosphane)copper(I) Complex of the Trihydridopyrazolylborate Ligand H3B(3,5-Ph(2)Pz)(-), European Journal of Inorganic Chemistry 2015(32): 5387-5394.
- Liu X., Akerboom S., Askes S.H.C., Mutikainen I. & Bouwman E. (2015), A novel coordination network of Tb(III) with 2-hydroxy-trimesic acid showing very intense photoluminescence, INORGANIC CHEMISTRY COMMUNICATIONS 61: 60-63.
- Ording-Wenker E.C.M., Siegler M.A. & Bouwman E. (2015), Coordination of new disulfide ligands to Cu-I and Cu-II: Does a Cu-II mu-thiolate complex form?, Inorganica Chimica Acta 428: 193-202.
- Terrade F.G., Verkuijl B. & Bouwman E. (2015), Process for manufacturing acrylic acid ( octrooi nr. EP15201469), (Leiden University). [patent].
- Ording-Wenker E.C.M., Plas van der Plas M., Siegler M.A., Guerra C.F. & Bouwman E (2014), Protonation of a Biologically Relevant Cu-II mu-Thiolate Complex: Ligand Dissociation or Formation of a Protonated Cu-I Disulfide Species?, Chemistry-a European Journal 20(51): 16913-16921.
- Akerboom S., Hazenberg E.T., Schrader I., Verbeek S.F., Mutikainen I., Fu W.T. & Bouwman E. (2014), o-Oxazolinyl- and o-Thiazolinylphenol as Antennae in Luminescent Eu-III and Tb-III Complexes, European Journal of Inorganic Chemistry (28): 4896-4906.
- Ording-Wenker E.C.M., Plas M. van der, Siegler M.A., Bonnet S.A., Bickelhaupt F.M., Guerra C.F. & Bouwman E. (2014), Thermodynamics of the Cu-II mu-Thiolate and Cu-I Disulfide Equilibrium: A Combined Experimental and Theoretical Study, Inorganic Chemistry 53(16): 8494-8504.
- Raoufmoghaddam S., Rood M.T.M., Buijze F.K.W., Drent E. & Bouwman E. (2014), Catalytic Conversion of gamma-Valerolactone to epsilon-Caprolactam: Towards Nylon from Renewable Feedstock, ChemSusChem 7(7): 1984-1990.
- Limburg B., Laisne G., Bouwman E. & Bonnet S. (2014), Enhanced Photoinduced Electron Transfer at the Surface of Charged Lipid Bilayers, Chemistry-a European Journal 20(29): 8965-8972.
- Akerboom S., Meijer M.S., Siegler M.A., Fu W.T. & Bouwman E. (2014), Structure, photo- and triboluminescence of the lanthanoid dibenzoylmethanates: HNEt3[Ln(dbm)(4)], JOURNAL OF LUMINESCENCE 145: 278-282.
- Akerboom S., Elshout J.J.M.H. van den, Mutikainen I., Siegler M.A., Fu W.T. & Bouwman E. (2013), Substituted Phenanthrolines as Antennae in Luminescent Eu-III Complexes, European Journal of Inorganic Chemistry 2013(36): 6137-6146.
- Ording E.C.M., Siegler M.A., Lutz M. & Bouwman E. (2013), Cu-I Thiolate Reactivity with Dioxygen: The Formation of Cu-II Sulfinate and Cu-II Sulfonate Species via a Cu-II Thiolate Intermediate, Inorganic Chemistry 52(22): 13113-13122.
- Akerboom Sebastiaan, van den Elshout Jos J. M. H., Mutikainen Ilpo, Fu Wen Tian & Bouwman Elisabeth (2013), 1-Methyl-1,10-phenanthrolin-2(1H)-one (L) as a ligand to Eu(III): Crystal structure and luminescent properties of [Eu(L)(3)(NO3)(3)], Polyhedron 64: 106-109.
- Raoufmoghaddam S., Drent E. & Bouwman E. (2013), Chemo- and Regioselective Homogeneous Rhodium-Catalyzed Hydroamidomethylation of Terminal Alkenes to N-Alkylamides, ChemSusChem 6(9): 1759-1773.
- Bahreman A., Limburg B., Siegler M.A., Bouwman E. & Bonnet S.A. (2013), Spontaneous Formation in the Dark, and Visible Light-Induced Cleavage, of a Ru-S Bond in Water: A Thermodynamic and Kinetic Study, Inorganic Chemistry 52(16): 9456-9469.
- Mooibroek T.J., Wenker E.C.M., Smit W., Mutikainen I., Lutz M. & Bouwman E. (2013), Homogeneous Hydrogenation and Isomerization of 1-Octene Catalyzed by Nickel(II) Complexes with Bidentate Diarylphosphane Ligands, Inorganic Chemistry 52(14): 8190-8201.
- Raoufmoghaddam S., Drent E. & Bouwman E. (2013), Process to prepare epsilon-caprolactam ( octrooi nr. EP13162426), (Leiden University). [patent].
- Raoufmoghaddam S., Drent E. & Bouwman E. (2013), Rhodium-Catalyzed Homogeneous Reductive Amidation of Aldehydes, Advanced Synthesis and Catalysis 355(4): 717-733.
- Albada G.A. van, Ghazzali M., Al-Farhan K., Bouwman E. & Reedijk J. (2013), Three new pyridine-2,6-dicarboxylate copper(II) compounds with coordinated pyrimidine-based ligands: Synthesis, characterization and crystal structures, Polyhedron 52: 1059-1064.
- Gamba I., Mutikainen I., Bouwman E., Reedijk J. & Bonnet S. (2013), Synthesis and Characterization of Copper Complexes of a Tetrapyridyl Ligand, and Their Use in the Catalytic Aerobic Oxidation of Benzyl Alcohol, European Journal of Inorganic Chemistry (1): 115-123.
- Postma R., Rijn J.A. van, Bouwman E. & Drent E. (2012), Process for the preparation of an allyl alkyl ether by catalytic allylation ( octrooi nr. US20120190811A1), (Leiden University). [patent].
- Akerboom S., Fu W.T., Lutz M. & Bouwman E. (2012), Crystal structure and luminescence of complexes of Eu(III) and Tb(III) with furan-2,5-dicarboxylate, Inorganica Chimica Acta 387: 287-294.
- Mooibroek T.J., Bouwman E. & Drent E. (2012), Mechanistic Study of the Oxidative Carbonylation of Methanol Catalyzed by Palladium Diphosphane Complexes with Nitrobenzene as Oxidant, European Journal of Inorganic Chemistry (9).
- Limburg B., Bouwman E. & Bonnet S. (2012), Molecular water oxidation catalysts based on transition metals and their decomposition pathways, Coordination Chemistry Reviews 256(15-16).
- Mooibroek T.J., Bouwman E. & Drent E. (2012), Mechanistic Study of the L2Pd-Catalyzed Reduction of Nitrobenzene with CO in Methanol: Comparative Study between Diphosphane and 1,10-Phenanthroline Complexes, ORGANOMETALLICS 31(11).
- Berding J., Paridon J.A. van, Rixel V.H.S. van & Bouwman E. (2011), [NiX2(NHC)(2)] Complexes in the Hydrosilylation of Internal Alkynes, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2011(15): 2450-2458.
- Bouwman E. (20 May 2011), Kleurrijk en veelzijdig (Inaugural address. Leiden Institute of Chemistry, Faculty of Science, Universiteit Leiden).
- van Rijn J.A., Goure E., Siegler M.A., Spek A.L., Drent E. & Bouwman E. (2011), The intriguing substitution behavior of CO with bidentate phosphine ligands induced by a gem-dialkyl effect, Journal of Organometallic Chemistry 696(9).
- Mooibroek T.J., Schoon L., Bouwman E. & Drent E. (2011), Carbonylation of Nitrobenzene in Methanol with Palladium Bidentate Phosphane Complexes: An Unexpectedly Complex Network of Catalytic Reactions, Centred around a Pd-imido Intermediate, Chemistry-a European Journal 17(47).
- van Albada G.A., Ghazzali M., Al-Farhan K., Bouwman E. & Reedijk J. (2011), Three new pyridine-2,6-dicarboxylate copper(II) compounds with coordinated pyridine-based ligands: Synthesis, characterisation and crystal structures, Polyhedron 30(16).
- den Hartog R., Harvey M.R., Hummel J.J.A., van der Pol S.T., Mutikainen I., van Albada G.A. & Bouwman E. (2011), Co(II), Zn(II) and Cu(II) compounds with 1,4; 1,3 or 1,2-bis-(benzimidazole-1-yl-methylene)-benzene as a flexible spacer ligand: Synthesis, characterization and X-ray structures of some polynuclear species, 376(1).
- van Rijn J.A., Guijt M.C., de Vries D., Bouwman E. & Drent E. (2011), Scope of the allylation reaction with RuCp(PP)+ catalysts: changing the nucleophile or allylic alcohol, Applied Organometallic Chemistry 25(3).
- van Rijn J.A., Guijt M.C., Bouwman E. & Drent E. (2011), Selective O-allylation of bisphenol A: toward a chloride-free route for epoxy resins, Applied Organometallic Chemistry 25(3).
- Mooibroek T.J., Lutz M., Spek A.L. & Bouwman E. (2010), Structure elucidation of the unprecedented asymmetric bis-chelate complex [Pd(1,3-bis(di(o-methoxy-m-methylphenyl)phosphino)propane)(2)](2+) in the solid state and in solution, DALTON TRANSACTIONS 39(45): 11027-11034.
- Berding J., Lutz M., Spek A.L. & Bouwman E. (2010), Nickel N-heterocyclic carbene complexes in the vinyl polymerization of norbornene, Applied Organometallic Chemistry 25(1): 76-81.
- Rijn J.A. van, Dunnen A. den, Bouwman E. & Drent E. (2010), Palladium-diphosphine complexes as catalysts for allylations with allyl alcohol, Journal of Molecular Catalysis a-Chemical 329(1-2).
- Koper M.T.M. & Bouwman E. (2010), Electrochemical Hydrogen Production: Bridging Homogeneous and Heterogeneous Catalysis, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH 49(22).
- Rijn J.A. van, Bouwman E. & Drent E. (2010), Immobilization of ruthenium catalysts for allylations with allyl alcohol, Journal of Molecular Catalysis a-Chemical 330(1-2).
- Mooibroek T.J., Bouwman E., Lutz M., Spek A.L. & Drent E. (2010), NMR Spectroscopic Studies of Palladium(II) Complexes of Bidentate Diphenylphosphane Ligands with Acetate and Tosylate Anions: Complex Formation and Structures, European Journal of Inorganic Chemistry (2).
- Rijn J.A. van, Stapele E. van, Bouwman E. & Drent E. (2010), Remarkable activity of the isomerization catalyst [RuCp(PPh3)(2)](OTs) in O-allylation of phenol with allyl alcohol, Journal of Catalysis 272(2).
- Angamuthu R., Byers P, Lutz M., Spek A.L. & Bouwman E. (2010), Electrocatalytic CO2 Conversion to Oxalate by a Copper Complex, SCIENCE 327(5963).
- Angamuthu R., Gelauff L. L., Siegler M. A., Spek A & Bouwman E. (2009), A molecular cage of nickel(II) and copper(I): a [{Ni(L)2}2(CuI)6] cluster resembling the active site of nickel-containing enzymes, Chemical Communications (19): 2700-2702.
- Berding J., Lutz M., Spek A & Bouwman E. (2009), Synthesis of Novel Chelating Benzimidazole-Based Carbenes and Their Nickel(II) Complexes: Activity in the Kumada Coupling Reaction, ORGANOMETALLICS 28(6): 1845-1854.
- Berding J., van Dijkman T. F., Lutz M., Spek A & Bouwman E. (2009), N-donor functionalized N-heterocyclic carbene nickel(II) complexes in the Kumada coupling, Dalton Transactions (35): 6948-6955.
- Angamuthu R. & Bouwman E. (2009), Reduction of protons assisted by a hexanuclear nickel thiolate metallacrown: protonation and electrocatalytic dihydrogen evolution, PHYSICAL CHEMISTRY CHEMICAL PHYSICS 11(27): 5578-5583.
- van Rijn J. A., Lutz M., von Chrzanowski L. S., Spek A, Bouwman E. & Drent E. (2009), Cationic Ruthenium-Cyclopentadienyl-Diphosphine Complexes as Catalysts for the Allylation of Phenols with Allyl Alcohol; Relation between Structure and Catalytic Performance in O- vs. C-Allylation, Advanced Synthesis and Catalysis 351(10): 1637-1647.
- Berding J., Kooijman H., Spek A & Bouwman E. (2009), Another silver complex of 1,3-dibenzylimidazol-2-ylidene: Solution and solid-state structures, Journal of Organometallic Chemistry 694(14): 2217-2221.
- van Rijn J. A., Siegler M. A., Spek A, Bouwman E. & Drent E. (2009), Ruthenium-Diphosphine-Catalyzed Allylation of Phenols: A gem-Dialkyl-Type Effect Induces High Selectivity toward O-Allylation, ORGANOMETALLICS 28(24): 7006-7014.
- van Rijn J. A., Marques-Gallego P., Reedijk J., Lutz M., Spek A & Bouwman E. (2009), A novel ruthenium(III) complex with a tridentate dianionic P,O,O-ligand showing high cytotoxic activity, Dalton Transactions (48): 10727-10730.
- Prasad M.R., Hamdy M.S., Mul G., Bouwman E. & Drent E. (2008), Efficient catalytic epoxidation of olefins with silylated Ti-TUD-1 catalysts, Journal of Catalysis 260: 288-294.
- Tanase S., Aromi G., Bouwman E., Kooijman H., Spek A.L. & Reedijk J. (2005), New routes to manganese higher-nuclearity topologies: synthesis of the cluster [Mn8(4-O)4(phpz)8(thf)4], Chemical Communications : 3147-3149.
- Tanase S., Bouwman E., Long G.J., Shahin A.M., Mills A.M., Spek A.L. & Reedijk J. (2004), Acid-base self-assembly chemistry and hydrogen bonding interactions resulting in the formation of a tetranuclear aggregate containing four crystallographically non-equivalent Fe-III centers, European Journal of Inorganic Chemistry 2004(23): 4572-4578.
- Wu J.Z., Bouwman E., Mills A.M., Spek A.L. & Reedijk J. (2004), Manganese(II) complexes of a set of 2-aminomethylpyridine-derived ligands bearing a methoxyalkyl arm: syntheses, structures and magnetism, Inorganica Chimica Acta 357(9): 2694-2702.
- Wu J.Z., Bouwman E. & Reedijk J. (2004), Chelating ligands as powerful additives to manganese driers for solvent-borne and water-borne alkyd paints, Progress in Organic Coatings 49(2): 103-108.
- Tanase S., Bouwman E. & Reedijk J. (2004), Role of additives in cobalt-mediated oxidative crosslinking of alkyd resins, Applied Catalysis a-General 259(1): 101-107.
- Drift R.C. van der, Vailati M., Bouwman E. & Drent E. (2000), Two reactions of allylic alcohols catalysed by ruthenium cyclopentadienyl complexes with didentate phosphine ligands: isomerisation and ether formation, Journal of Molecular Catalysis a-Chemical : 163-177.
- Bouwman E., Henderson R.K., Reedijk J., Veldman N. & Spek A.L. (1999), Synthesis of the ligand N,N '-bis(2-tert-butylthiobenzenylidene)-diethylenetriamine; its reactivity with nickel(II) salts, Inorganica Chimica Acta 287(1): 105-108.
- Bouwman E., Henderson R.K., Spek A.L. & Reedijk J. (1999), Spontaneous Assembly of a Novel Tetranuclear Ni-Fe by Complex Reshuffling of Ligands and Oxidation States, European Journal of Inorganic Chemistry : 217-219.
- Hoogenraad M., Ramkisoensing K., Kooijman H., Spek A.L., Bouwman E., Haasnoot J.G. & Reedijk J. (1998), Synthesis and characterisation of the new complex tris[(2-oxazolinyl)phenolato]manganese(III) and its use as a catalyst in oxidation reactions, 279: 217-220.
- Angulo I.M., Kluwer A.M. & Bouwman E. (1998), Fast and selective homogeneous hydrogenation with nickel(II) phosphane catalysts, Chemical Communications (24): 2689-2690.
- Kaasjager V.E., Henderson R.K., Bouwman E., Lutz M., Spek A.L. & Reedijk J. (1998), A structural model for [Fe]-only hydrogenases, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH 37: 1668-1670.
- Bouwman E., Henderson R.K., Powell A.K., Reedijk J., Smeets W.J.J., Spek A.L., Veldman N. & Wocadlo S. (1998), Anion dependent deprotection of a thioether group in Schiff base NS2 ligands results in new mononuclear and dinuclear thiolato nickel complexes, JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (20): 3495-3499.
- Smeets W.J.J., Spek A.L., Henderson R.K., Bouwman E. & Reedijk J. (1997), [N,N'-bis(2-thiobenzylidene)-1,2-phenylenediaminato]nickel(II), Acta Crystallographica Section C: Structural Chemistry 53: 1564-1566.
- Henderson R.K., Bouwman E., Spek A.L. & Reedijk J. (1997), A unique mononuclear nickel disulfonato complex obtained by oxidation of a mononuclear nickel dithiolate complex, Inorganic Chemistry 36(21): 4616-4617.
- Henderson R.K., Bouwman E., Reedijk J. & Powell A.K. (1996), [N,N'-bis(2-thiobenzylidene)-1,2-dimethyl-4,5-phenylenediaminato]nickel(II), Ni(tsaldimph), ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 52: 2696-2698.
- Bouwman E., Evans P., Graaff R.A.G. de, Kooijman H., Poinsot R., Rabu P., Reedijk J. & Spek A.L. (1995), Synthesis and spectroscopy of coordination-compounds of a versatile bridging ligand - molecular-structures of the dinuclear compounds [co-2(bdnol)(ncs)(3)], [zn-2(bdnol)cl(ncs)(2)], and [cu(bdnol)(no3)(3)] and of the polymeric copper(i) compound [cu-2(hbdnol)(ncs)(2)], INORGANIC CHEMISTRY 34(25): 6302-6311.
- Bouwman E. & Reedijk J. (1994), Neutral transition metal complexes with the tridentate ligand 4-(5-methyl-4-imidazolyl)-3-thiabutanoic acid. A series of isostructural octahedral compounds, Inorganica Chimica Acta 215(1-2): 151-157.
- Bouwman E., Evans P., Kooijman H., Reedijk J. & Spek A.L. (1993), Novel trinuclear and dinuclear nickel coordination compounds with a new pentadentate ligand. Crystal structures of [Ni3(bdnol)EtOH)Cl5] and [Ni2(bdnol)Cl3], Journal of the Chemical Society, Chemical Communications (23): 1746-1748.
- Cabral M.F., Cabral J. de O., Bouwman E., Driessen W.L., Reedijk J., Turpeinen U. & Hämälainen R. (1992), Cyclic voltammetric studies of copper(II) complexes with some bis(imidazole)bis(thioether) ligands. The x-ray crystal structure of (1, 6-bis-(5(4)-imidazolyl)-2, 5-dithiahexane)dichlorocopper(II), Inorganica Chimica Acta 196(2): 137-144.
- Bouwman E., Driessen W.L., Koolhaas G.J.A.A., Steenbergen A.C. van, Reedijk J., Dartmann M. & Krebs B. (1991), Coordination compounds with the N2S donor ligand 1,3-bis(5'-methyl-4'-imidazolyl)-2-thiapropane (sbi). The X-ray structure of [ZnCl2(sbi)], Inorganica Chimica Acta 189(2): 253-257.
- Bouwman E., Peters J.A., Bekkum H. van & Gorter S. (1991), Structure of sodium 2-keto-d-gluconate monohydrate (sodium d-arabino-2-hexulosonate monohydrate), ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 47: 1155-1158.
- Verweij P.D., Sital S., Bouwman E., Driessen W.L., Reedijk J. & Wood J.S. (1991), Transition-metal compounds of a chelating imidazole-thioether-amine ligand - Crystal and molecular-structures of (4-(5-methyl-4-imidazolyl)-1-amino-3-thiabutane)di(chloro)copper(ii), bis(4-(5-methyl-4-imidazolyl)-1-amino-3-thiabutane)copper(ii) dichloride dihydrate, and bis(4-(5-methyl-4-imidazolyl)-1-amino-3-thiabutane)cobalt(iii) tris(tetrafluoroborate), Inorganica Chimica Acta 182(2): 187-195.
- Steenbergen A.C. van, Bouwman E., Graaff R.A.G. de, Driessen W.L. & Reedijk J. (1990), Copper Co-ordination compounds of a chelating imidazole- thioether ligand. The molecular structures of [1,3-Bis(5-methyl-4-imidazolyl)-2-thiapropane]-bis(nitrato)copper(II) and Bis[1,3-bis(5-methyl-4-imidazolyl)-2-thiapropane]-copper(II) Bis(tetrafluoroborate)-ethanol(1/2), Journal of the Chemical Society, Dalton Transactions (11): 3175-3182.
- Bouwman E., Driessen W.L., Reedijk J., Smykally C., Smits J.M.M., Beurskens P.T., Laschi F. & Zanello P. (1990), A unique bromo- and thioether-bridged tetranuclar mixed-valence copper(I)-copper(II) compound with the N,S-donor ligand 4-((ethylthio)methyl)-5-methylimidazole, Inorganic Chemistry 29(24): 4881-4886.
- Zoeteman M., Bouwman E., Graaff R.A.G. de, Driessen W.L., Reedijk J. & Zanello P. (1990), Synthesis and spectroscopy of copper(ii) compounds of a chelating imidazole thioether ligand - molecular-structures of (1,5-bis(4-imidazolyl)-3-thiapentane)dichlorocopper(ii), (1,5-bis(4-imidazolyl)-3-thiapentane)bis(thiocyanato-n)copper(ii), and bis[(mu-chloro)(1,5-bis(4-imidazolyl)-3-thiapentane)copper(ii)] bis(perchlorate), INORGANIC CHEMISTRY 29(18): 3487-3492.
- Bouwman E., Driessen W.L. & Reedijk J. (1990), Model systems for type I copper proteins: structures of copper coordination compounds with thioether and azole-containing ligands, Coordination Chemistry Reviews 104(1): 143-172.
- Tullemans A.H.J., Bouwman E., Graaff R.A.G. de, Driessen W.L. & Reedijk J. (1990), Dioxygen uptake and catalytic activity of some monomeric copper(II) compounds containing an N,S donor ligand. The X‐ray structure of bis[5‐methyl‐4‐(ethylthiomethyl)imidazole]bis(tetrafluoroborato)copper(II)†, Recueil des Travaux Chimiques des Pays-Bas 109(2): 70-76.
- Cabral M.F., Cabral J. de O., Bouwman E., Driessen W.L. & Reedijk J. (1990), Redox properties of five-coordinate and six-coordinate chlorobis(imidazole)-bis(thioether)copper(II) complexes, Inorganica Chimica Acta 167(2): 205-211.
- Rijn J. van, Bouwman E., Empfield J.R., Driessen W.L. & Reedijk J. (1989), Coordination compunds with a biomimetic N2S2 ligand, resulting in ling metal-thioether bonds. The crystal and molecular structure of (1,7-bis(5-methyl-4-imidazolyl)-2,6-dithiaheptane]bus(thiocyanato-N)cobalt(II), Polyhedron 8(15): 1965-1970.
- Bouwman E., Westheide C.E., Driessen W.L. & Reedijk J. (1989), Synthesis and spectroscopic studies on transition-metal nitrates and thiocyanates of a chelating imidazole-thioether ligand - The crystal-structures of diaquabis[5-methyl-4-(ethyl-mercaptomethyl)imidazole]nickel(ii) dinitrate, diaquabis[5-methyl-4-(ethyl-mercaptomethyl)imidazole]copper(ii) dinitrate and bis[5-methyl-4-(ethyl-mercaptomethyl)imidazole]bis(thiocyanato-n)cobalt(ii), Inorganica Chimica Acta 166(2): 291-299.
- Bouwman E. & Driessen W.L. (1989), Structure of the ns-donor ligand 4-(ethylthiomethyl)-5-methylimidazole, ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 45: 1792-1794.
- Volbeda A., Feiters M.C., Vincent M.G., Bouwman E., Dobson B., Kalk K.H., Reedijk J. & Hol W.G.J. (1989), Spectroscopic investigations of panulirus-interruptus hemocyanin in the crystalline state, EUROPEAN JOURNAL OF BIOCHEMISTRY 181(3): 669-673.
- Bouwman E., Tenhove J.C., Driessen W.L. & Reedijk J. (1988), Transition-metal coordination-compounds of a chelating imidazole thioether ligand - The X-ray crystal-structure of (1,6-bis(4(5)-imidazolyl)-2,5-dithiahexane)bis(nitrato)copper(ii), POLYHEDRON 7(24): 2591-2595.
- Bouwman E. & Driessen W.L. (1988), The synthesis and characterization of some new thioether-imidazole containing ligands, SYNTHETIC COMMUNICATIONS 18(13): 1581-1588.
- Bouwman E., Day R., Driessen W.L., Tremel W., Krenbs B., Wood J.S. & Reedijk J. (1988), Two different copper(II) coordination geometries imposed by two closely related chelating imidazole-thioeter (N2S2) ligands. Crystal structure of (1,6-bis(4-imidazolyl)-2,5-dithiahexane)chlorocopper(II) tetrafluoroborate, (1,6-bis(5-methyl-4-imidazolyl)-2,5-dithiahexane)chloro(tetrafluoroborato) copper(II), and (1,6-bis(5-methyl-4-imidazoly)-2,5-dithiahexane)nitrato(thiocyanato-N)copper(II), Inorganic Chemistry 27(25): 4614-4618.
- Bouwman E., Burik A., Hove J.C. ten, Driessen W.L. & Reedijk J. (1988), Metal chloride compounds of chelating imidazole thioether ligands. Crystal structures of dicholoro-(1,6-bis(5-methyl-4-imidazolyl)-2,5-dithiahexane)copper(II) and {chloro-(1,6-bis(5-methyl-4-imidazolyl)-2,5-dithiahexane)copper(II)} chloride dihydrate, Inorganica Chimica Acta 150(1): 125-131.
- Spek A.L., Duisenberg A.J.M., Bouwman E., Driessen W.L. & Reedijk J. (1988), Structure of bis[1,3-bis(5-methyl-4-imidazolyl)-2-thiapropane-n,n,s]nickel(ii) hexafluorosilicate pentahydrate, ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 44: 1569-1572.
- Bouwman E. & Driessen W.L. (1988), An unusual dinuclar cobalt dioxygen complex with a tetradentate thioether imidazole containing ligand. Structure of [Co2(Bidhx)2(O2)(OH)](NO3)3, Journal of the American Chemical Society 110(13): 4440-4441.
- Bouwman E., Driessen W.L. & Reedijk J. (1988), Synthesis, spectroscopy, and crystal-structure of a thiocyanato-bridged mixed-valence copper(i) copper(ii) compound with the ligand 1,6-bis(5'-methylimidazol-4'-yl)-2,5-dithiahexane, JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (5): 1337-1340.
- Bouwman E., Wood J.S., Day R., Tenhove J.C., Driessen W.L. & Reedijk J. (1988), Structure of diaqua[1,6-bis(4-imidazolyl)-2,5-dithiahexane]nickel(ii) dinitrate, ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 44: 644-646.
- Bouwman E., Gelder R. de, Graaff R.A.G. de, Driessen W.L. & Reedijk J. (1988), Transition-metal coordination-compounds of a chelating imidazole-thioether ligand - The molecular-structure of diisothiocyanato[1,6-bis(5-methyl-4-imidazolyl)-2,5-dithiahexane]nickel(ii), RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY 107(3): 163-166.
- Bouwman E., Driessen W.L. & Reedijk J. (1987), Modeling type-1 copper proteins with thioether-containing and imidazole-containing ligands, RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY 106(6-7): 369-369.
- Paap F., Bouwman E., Driessen W.L., Graaff R.A.G. de & Reedijk J. (1985), Spectroscopic and magnetic-properties of cobalt(ii) and nickel(ii) clusters obtained from 1-(hydroxymethyl)-3,5-dimethylpyrazole - x-ray structure of tetrakis[chloro(mu-3-3,5-dimethyl-n-oxymethylpyrazolato-n2,mu-3-o)-(ethanol)nickel(ii)], JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (4): 737-741.
- Bouwman E., Driessen W.L. & Reedijk J. (1985), Coordination-compounds of a pentadentate pyrazole derivative of diaminopropane - crystal-structure of aqua(n,n,n'-tris((3,5-dimethylpyrazol-1-yl)methyl)-1,3-diaminopropane)cobalt(ii) diperchlorate hydrate, [co(ap3d)(h2o)](clo4)2.h2o, INORGANIC CHEMISTRY 24(26): 4730-4733.
- Bouwman E., Driessen W.L., Graaff R.A.G. de & Reedijk J. (1984), Structure of dichlorobis(3,5-dimethylpyrazole-n-2)zinc(ii), [zncl2(c5h8n2)2], ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 40(SEP): 1562-1563.
No relevant ancillary activities