The central theme of Rik Mom’s research group is to identify what the electrode-electrolyte interface looks like when electrocatalysis is taking place. Using specialized forms of Raman and X-ray spectroscopy, we study the chemical state and bonding environment of the electrode surface and near-surface…

In most applications, electrocatalysts exhibit a large surface area to volume ratio, for example using nanoparticles.

Marc Koper has been selected as one of the six new fellows in 2015 of the International Society of Electrochemistry.

Marc Koper, Professor of Catalysis and Surface Chemistry, has been elected as President Elect of the International Society of Electrochemistry (ISE). He will be President Elect for two years starting January 2019, followed by two years as President and two years as Immediate Past President.

The research described in this thesis focused on the preparation of S/N functionalized carbene ligands and their transition metal complexes, and the exploration of their application as electrocatalysts for proton reduction.

Marc Koper, Professor of Catalysis and surface chemistry, has won the Brian Conway Prize for Physical Electrochemistry of the International Society of Electrochemistry (ISE). The ISE jury chose Koper as the winner due to his outstanding contributions in the field of physical electrochemistry.

This thesis is a collection of experimental attempts to enhance photoluminescence of fluorescent molecules and quantum dots with single gold nanorods (GNRs) and relevant applications.

Promotor: M.T.M. Koper, Co-Promotor: L.B.F. Juurlink

In this dissertation, the synthesis and characterization of a series of iron complexes based on different ligand platforms are described.

Promotor: M.T.M. Koper, Co-promotor: L. Juurlink

In this thesis we have discussed several parameters that affect the electrochemical conversion of enviromentaly harmful molecules such as nitrates and carbon dioxide to more valuable and less deleterious compounds, in order to cast light onto the mechanism of the reaction to achieve an efficient and…

Professor of Catalysis and Surface Chemistry Marc Koper has been appointed as member of the Koninklijke Nederlandse Akademie van Wetenschappen (KNAW). 'Very honourable, I see this as a confirmation of my work,’ says Koper.

In this dissertation iron-based homogeneous catalysts were synthesized, characterized and investigated for water oxidation activity.

PhD Defence

During the 20th anniversary meeting of the Netherlands' Catalysis and Chemistry Conference, Marc Koper received the Netherlands Catalysis and Chemistry Award. ‘The ultimate candidate for the prize’, it says in one of the recommendation letters.

Twenty years from now, the world population is estimated to be around 8.7 billion people, compared to the current 7.3 billion. In combination with the improvements in living standards and the corresponding growth in consumption, this will result in an enormous increase in the demand for food, consumables,…

The focus throughout this thesis will be on gathering fundamental studies of the detailed structure and composition of the electrode/electrolyte interface effect on the rate and mechanism of key electrocatalytic reactions.

Lecture

Chemist Prof. Marc Koper was awarded the Carl Wagner Memorial Award of the Electrochemical Society.

Through an NWO grant, chemist Rik Mom has received a tenure track position at the Leiden Institute of Chemistry, where he obtained his PhD cum laude in 2017. Mom will study the storage of sustainable energy by means of splitting water. Using new methods, he will investigate on an atomic scale which…

Twenty years from now, the world population is estimated to be around 9 billion people (now 7.8 billion). In combination with the improvements in living standards and the corresponding growth in consumption, this will result in an enormous increase in the demand for food, consumables, water and energy.…

How are links between macro-invertebrate diversity and ecosystem functioning influenced by anthropogenic pressures?

In this work, we illustrate unconventional approaches towards the fabrication of edge functionalized graphene nanostructures and bidimensional architectures in polymeric and metallic supports, with an outlook towards molecular sensing devices.

Leiden University has developed a radically different method for large scale production of diverse nanoparticles and their alloys.

A full overview of CASC PhD theses.

The E2CB programme has been launched to bring CO2 emissions to zero by 2050. The goal: to produce all raw materials for the chemical industry from sustainable sources. Professor of Electrochemistry Marc Koper is involved in the project.

The research aim of the Catalysis and Surface Chemistry group headed by Prof. Marc Koper is to probe and understand chemical reactions on well-defined, mostly single crystalline, surfaces at the molecular level.

Leiden chemist Marc Koper is the winner of the 2017 Faraday Medal for his significant contribution to electrochemistry, from fundamental science to practical application.

Research of the Leiden Institute of Chemistry into the development of a sustainable fuel cell has accidentally resulted in an exceptionally efficient catalyst for the production of hydrogen peroxide. The catalyst, discovered by Dennis Hetterscheid and PhD candidate Michiel Langerman, may lead to a more…

Electrochemist Marc Koper has won a special award: the Allen J. Bard Award in Electrochemical Science. 'Allen Bard has always been a great example to me, so it is extra special to win this award.' The award will be granted by the Electrochemical Society, at their half-yearly conference next year in…

Research at the Catalysis and Surface Chemistry group is comprised of the following research themes:

Science, Leiden Institute of Chemistry (LIC)

The main research theme in the group of Dennis Hetterscheid is to understand and mimic bioinorganic multi-electron processes that are relevant to our future energy infrastructure. Reduction of protons generates hydrogen that can be used as a chemical fuel. Alternatively to gaseous hydrogen, the reduction…

Science, Leiden Institute of Chemistry (LIC)

The electrochemical reduction of a group of organic compounds on platinum is strongly dependent on the arrangement of the atoms in the platinum surface. Christoph Bondue, postdoc in Marc Koper's group, published this in Nature Catalysis on 4 March. The reduction of such compounds is an important process…

Both Leon Jacobse and Thom Hersbach from Marc Koper's research group obtained their PhDs cum laude. They both investigated changes on the surface of a platinum electrode. Jacobse studied this at a positive voltage, Hersbach at a negative voltage. Platinum has the potential to convert renewable energy…

Leiden chemists Marc Koper and Ian McCrum have discovered that the degree to which a metal binds to the oxygen atom of water is decisive for how well the chemical conversion of water to molecular hydrogen takes place. This insight helps to develop better catalysts for the production of sustainable hydrogen,…

The transition to new and renewable energy sources should be completed by 2050. Researchers in various disciplines at Leiden University are conducting unique research that will help us make this transition and reduce CO2 emissions.

Electrocatalysis will play an increasingly important role in future in the transition to more sustainable energy. Thanks to chemist Isis Ledezma Yanez, we now know more about the hydrogen evolution process. PhD defence on the 9th of June.

Ionic liquids are important in scientific research because they can apply a lot of charge over a surface. Leiden physicists have now found that the charging process of ionic liquids purely depends on opposite charges attracting each other. Chemical reactions are sometimes involved, but not essential.…

Physical chemist Rik Mom developed a revolutionary way to investigate catalysts in action in detail. For this work he received the distinction cum laude during his PhD defence on 29 June.

Yuvraj Birdja converted CO2 to formic acid to store energy in a sustainable way, with different catalysts. With this new knowledge, scientists are a step closer in industrially converting CO2 to chemicals and fuels. This can help reduce CO2 emission and the greenhouse effect.

How can rare and expensive materials be used more efficiently to produce cleaner and cheaper fuel? Under the guidance of Marc Koper, Professor of Catalysis and Surface Chemistry, international teams of scientists have published 3 articles in Nature Communications.

An overview of awards and prizes granted to our staff and students in 2018, as well as special appointments and royal distinctions.